The easiest fast way without huge markup for newbies, that I would recommend...
1 Create a new wallet for free at
https://blockchain.info/
2 Go to
https://www.bitinstant.com
3 Select Walmart in the pay from box
4 Select Bitcoin address from pay to box
5 Fill out the info asked for, use your address from the wallet you created. When selecting amount to pay remember there will be an additional 4 dollars added on.
6 Follow through the prompts and select the Walmart closest to you, it will generate a payment slip with the info you need. It will send the payment slip to your email within 5 minutes, copy the info under zipzap biller info or have the slip accessible on your phone. The amount to pay here is the full amount you will pay at Walmart.
7 Go to Walmart grab a blue moneygram slip. Fill out your info in the top portion, fill the info from the payment slip into the bottom portion.
8 Hand it to the person at the counter and pay.
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